Jeremy Buch, 24, of Chillicothe and Timothy Newton II, 21, are charged with burglary and stealing of firearms.
The Livingston County Sheriff's Department says it recently began investigating a burglary at a home in the north east part of the county where firearms were stolen.
Investigators say digital cameras in the area caught the suspects and a vehicle breaking into the home.
A deputy spotted the vehicle on the 1100 block of Calhoun Street and arrested Buch.
Newton was arrested later in Chillicothe.
Investigators say a search of the home on Calhoun Street turned up six stolen firearms.
A seventh stolen gun was found at a property in southeastern Livingston County.